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Título : | A new monoclinic form of a Ru(II)/Fe(II) heterobimetallic complex : conformation, crystal packing and Hirshfeld surface. |
Autor : | Teixeira, Tamara Martir, Luiz Fernando Barbosa Oliveira, Katia Mara de Correa, Rodrigo de Souza |
Fecha de publicación : | 2021 |
Citación : | TEIXEIRA, T. et al. A new monoclinic form of a Ru(II)/Fe(II) heterobimetallic complex: conformation, crystal packing and Hirshfeld surface. Journal of Molecular Structure, v. 1236, artigo 130330, 2021. Disponível em: <https://www.sciencedirect.com/science/article/abs/pii/S0022286021004622>. Acesso em: 10 jun. 2021. |
Resumen : | Herein, a new monoclinic form (C2/c), Form H-II, of the heterobimetallic cis-[RuCl2(dppf)(bipy)] complex was obtained and compared in terms of molecular conformation, as well as intra and intermolecular geometries with two orthorhombic forms (Pna21) previously reported, Form S and H-I. The crystal packing of Form H-II is based on weak intermolecular interactions that were explored by Hirshfeld surface and 2D-fingerprint plots analysis, revealing the presence of weak H…H, C…H, C…C and Cl…H contacts that stabilize the crystal structure. As can be seen, the Form H-II differs from hydrate form (Form H-I), according water molecule location and crystal self-assembly. This found emphasizes the versatility of the studied Ru(II)/Fe(II) heterobimetallic complex in the crystal engineering field. |
URI : | http://www.repositorio.ufop.br/jspui/handle/123456789/14276 |
metadata.dc.identifier.uri2: | https://www.sciencedirect.com/science/article/abs/pii/S0022286021004622 |
metadata.dc.identifier.doi: | https://doi.org/10.1016/j.molstruc.2021.130330 |
ISSN : | 0022-2860 |
Aparece en las colecciones: | DEQUI - Artigos publicados em periódicos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
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ARTIGO_NewMonoclinicForm.pdf Restricted Access | 2,51 MB | Adobe PDF | Visualizar/Abrir |
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