Complete assignment of the 1H and 13C NMR spectra of the tetraisoprenylated benzophenone 15-epiclusianone.

Use este identificador para citar ou linkar para este item: http://www.repositorio.ufop.br/jspui/handle/123456789/7948

Título:	Complete assignment of the 1H and 13C NMR spectra of the tetraisoprenylated benzophenone 15-epiclusianone.
Autor(es):	Santos, Marcelo Henrique dos Nagem, Tanus Jorge Braz Filho, Raimundo Lula, Ivana Silva Speziali, Nivaldo Lucio
Data do documento:	2001
Referência:	SANTOS, M. H. dos et al. Complete assignment of the 1H and 13C NMR spectra of the tetraisoprenylated benzophenone 15-epiclusianone. Magnetic Resonance in Chemistry, Chichester, v. 39, n.3, p. 155-159, 2001. Disponível em: <http://onlinelibrary.wiley.com/doi/10.1002/mrc.795/full>. Acesso em: 20 mai. 2017.
Resumo:	An NMR study of 15-epiclusianone, 1-benzoyl-6-hydroxy-14,14-dimethyl-3,5,15-tri(3-methyl-2-butenyl)- bicyclo[3.3.1]non-1-ene-4,6-dione (1), a novel tetraisoprenylated benzophenone isolated from pericarp of fruits of Rheedia gardneriana, is described. In addition to conventional 1D NMR techniques, 2D shiftcorrelated NMR experiments [1H 1H-COSY, 1H 13C-HMQC-1J(C,H), 1H 13C-HMBC-nJ(C,H) (n = 2 and 3) and 1H 1H-NOESY] were used for 1H and 13C chemical shift assignments of this natural product. The 1D 13C NMR spectrum of 1 in the solid state was also obtained.
URI:	http://www.repositorio.ufop.br/handle/123456789/7948
Link para o artigo:	http://onlinelibrary.wiley.com/doi/10.1002/mrc.795/full
DOI:	https://doi.org/10.1002/mrc.795
ISSN:	1097-458X
Aparece nas coleções:	DEQUI - Artigos publicados em periódicos

Arquivos associados a este item:

Arquivo	Descrição	Tamanho	Formato
ARTIGO_CompleteAssignmentH.pdf Restricted Access		170,79 kB	Adobe PDF	Visualizar/Abrir