Thermal behaviour and isothermal kinetics of rhodium(II) acetate.
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Data
1997
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Resumo
The thermal decomposition of solid rhodium(II) acetate was studied by isothermal TG. Kinetic analysis of the isothermal data showed that the complex decomposition in the range 198.0-210.5°C occurs according to a Prout-Tompkins (An) law. The isothermal curves are better fitted using a non-linear least square method. The activation energy found was 16:2.7 kJ tool ~. At temperatures higher than 210.5°C the decomposition is strongly accelerated and no kinetic study was available.
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Thermal decomposition, Isothermal, Kinetics, Mechanism, Rhodium(II) carboxylates
Citação
BRAGA, M. M. et al. Thermal behaviour and isothermal kinetics of rhodium(II) acetate. Thermochimica Acta, v. 296, p. 141-148, 1997. Disponível em: <https://www.sciencedirect.com/science/article/pii/S004060319700021X>. Acesso em: 19 out. 2012.