A new monoclinic form of a Ru(II)/Fe(II) heterobimetallic complex : conformation, crystal packing and Hirshfeld surface.
dc.contributor.author | Teixeira, Tamara | |
dc.contributor.author | Martir, Luiz Fernando Barbosa | |
dc.contributor.author | Oliveira, Katia Mara de | |
dc.contributor.author | Correa, Rodrigo de Souza | |
dc.date.accessioned | 2021-12-21T18:20:46Z | |
dc.date.available | 2021-12-21T18:20:46Z | |
dc.date.issued | 2021 | pt_BR |
dc.description.abstract | Herein, a new monoclinic form (C2/c), Form H-II, of the heterobimetallic cis-[RuCl2(dppf)(bipy)] complex was obtained and compared in terms of molecular conformation, as well as intra and intermolecular geometries with two orthorhombic forms (Pna21) previously reported, Form S and H-I. The crystal packing of Form H-II is based on weak intermolecular interactions that were explored by Hirshfeld surface and 2D-fingerprint plots analysis, revealing the presence of weak H…H, C…H, C…C and Cl…H contacts that stabilize the crystal structure. As can be seen, the Form H-II differs from hydrate form (Form H-I), according water molecule location and crystal self-assembly. This found emphasizes the versatility of the studied Ru(II)/Fe(II) heterobimetallic complex in the crystal engineering field. | pt_BR |
dc.identifier.citation | TEIXEIRA, T. et al. A new monoclinic form of a Ru(II)/Fe(II) heterobimetallic complex: conformation, crystal packing and Hirshfeld surface. Journal of Molecular Structure, v. 1236, artigo 130330, 2021. Disponível em: <https://www.sciencedirect.com/science/article/abs/pii/S0022286021004622>. Acesso em: 10 jun. 2021. | pt_BR |
dc.identifier.doi | https://doi.org/10.1016/j.molstruc.2021.130330 | pt_BR |
dc.identifier.issn | 0022-2860 | |
dc.identifier.uri | http://www.repositorio.ufop.br/jspui/handle/123456789/14276 | |
dc.identifier.uri2 | https://www.sciencedirect.com/science/article/abs/pii/S0022286021004622 | pt_BR |
dc.language.iso | en_US | pt_BR |
dc.rights | restrito | pt_BR |
dc.title | A new monoclinic form of a Ru(II)/Fe(II) heterobimetallic complex : conformation, crystal packing and Hirshfeld surface. | pt_BR |
dc.type | Artigo publicado em periodico | pt_BR |
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