Tin(IV) compounds derivatives of reaction between Organotin(IV), SNCL4 and rutin trihydrate : characterization and hypolipidemic effects.
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2004
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Equimolar reactions involving SnClPh3, SnCl2Ph2, SnCl3Ph and SnCl4 and rutin trihydrate (Quercetin-3-
rutinoside) produced organotin(IV) polymers, which have been characterized by infrared spectroscopy, 'H,
n C and "9Sn NMR, Mössbauer spectroscopy, gel permeation chromatography (GPC), differential scanning
calorimetry (DSC) and microanalysis. The NMR ('Η, 13C) and "9Sn Mössbauer spectroscopy have revealed
dephenylation of the starting organotin(IV) materials. The overall data have revealed a six-coordination for
the Sn(IV) centre in solution as well as in solid state. DSC and GPC techniques have confirmed the formation
of macromolecules for those adducts with an average molar mass higher than 7.0x10' g/mol. The
hypolipidemic effect of total cholesterol reduction in male New Zealand rabbits was comparable to calcic
atorvastatin, a commercial drug for treatment of hyperlipidemic patients.
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MELLO, V. J. de et al. Tin(IV) compounds derivatives of reaction between Organotin(IV), SNCL4 and rutin trihydrate: characterization and hypolipidemic effects. Main Group Metal Chemistry, Israel, v. 27, n.6, p. 309-321, 2004. Disponível em: <https://www.degruyter.com/view/j/mgmc.2004.27.6/mgmc.2004.27.6.309/mgmc.2004.27.6.309.xml>. Acesso em: 20 mai. 2017.