Use este identificador para citar ou linkar para este item:
http://www.repositorio.ufop.br/jspui/handle/123456789/7342
Título: | Supramolecular aggregation in new crystals with nonlinear optical properties : 2-aminophenol-HClO4, 3-aminophenol-HClO4 and 4-aminophenol-HClO4. |
Autor(es): | Janczak, Jan Perpétuo, Genivaldo Julio |
Palavras-chave: | Crystal structure |
Data do documento: | 2009 |
Referência: | JANCZAK, J.; PERPÉTUO, G. J. Supramolecular aggregation in new crystals with nonlinear optical properties: 2-aminophenol-HClO4, 3-aminophenol-HClO4 and 4-aminophenol-HClO4. Solid State Sciences, v. 11, p. 1576-1581, 2009. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1293255809002337?np=y&npKey=d049c02c40ff7ad035e8e5f67cd129351385d277a6649f65d8a9b85bfdf80363>. Acesso em: 09 mar. 2017. |
Resumo: | Three new hybrid crystals of 2-aminophenol-HClO4 (2-AP-HClO4,1), 3-aminophenol-HClO4 (3-AP-HClO4, 2) and 4-aminophenol-HClO4 (4-AP-HClO4, 3) were obtained and their crystal structures determined. The 1 crystallises in centrosymmetric space group C2/c of monoclinic system while the other two (2 and 3) crystallise in the non-centro symmetric space groupP21 andP212121, respectively. The oppositely charged units of the crystals, i.e. positively charged 2-APHþ, 3-APHþ and 4-APHþ and ClO4 , interact viaweak Nþ–H/O and O– H/O hydrogen bonds forming 3D-supramolecular network. Relative to KDP the SHG efficiencies are 0.62 for 2 and 0.33 for 3, measured at 1064 nm using the Kurtz–Perry method. |
URI: | http://www.repositorio.ufop.br/handle/123456789/7342 |
Link para o artigo: | http://www.sciencedirect.com/science/article/pii/S1293255809002337?np=y&npKey=d049c02c40ff7ad035e8e5f67cd129351385d277a6649f65d8a9b85bfdf80363 |
DOI: | https://doi.org/10.1016/j.solidstatesciences.2009.06.024 |
ISSN: | 1293-2558 |
Aparece nas coleções: | DEFIS - Artigos publicados em periódicos |
Arquivos associados a este item:
Arquivo | Descrição | Tamanho | Formato | |
---|---|---|---|---|
ARTIGO_SupramolecularAggregationNew.pdf Restricted Access | 607,17 kB | Adobe PDF | Visualizar/Abrir |
Os itens no repositório estão protegidos por copyright, com todos os direitos reservados, salvo quando é indicado o contrário.