Use este identificador para citar ou linkar para este item: http://www.repositorio.ufop.br/handle/123456789/4166
Título: Thermal analysis and vibrational spectroscopic characterization of the boro silicate mineral datolite - CaBSiO4(OH).
Autor(es): Frost, Ray L.
Xi, Yunfei
Scholz, Ricardo Augusto
Lima, Rosa Malena Fernandes
Horta, Laura Frota Campos
López, Andrés
Palavras-chave: Thermal analysis
Thermal stability
Datolite
Silicate
Borate
Data do documento: 2013
Referência: FROST, R. L. et al. Thermal analysis and vibrational spectroscopic characterization of the boro silicate mineral datolite - CaBSiO4(OH). Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, v. 115, p. 376-381, 2013. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1386142513006161>. Acesso em: 07 out. 2014.
Resumo: The objective of this work is to determine the thermal stability and vibrational spectra of datolite CaBSiO4(OH) and relate these properties to the structure of the mineral. The thermal analysis of datolite shows a mass loss of 5.83% over a 700–775 °C temperature range. This mass loss corresponds to 1 water (H2O) molecules pfu. A quantitative chemical analysis using electron probe was undertaken. The Raman spectrum of datolite is characterized by bands at 917 and 1077 cm^-1 assigned to the symmetric stretching modes of BO and SiO tetrahedra. A very intense Raman band is observed at 3498 cm^-1 assigned to the stretching vibration of the OH units in the structure of datolite. BOH out-of-plane vibrations are characterized by the infrared band at 782 cm^-1. The vibrational spectra are based upon the structure of datolite based on sheets of four- and eight-membered rings of alternating SiO4 and BO3(OH) tetrahedra with the sheets bonded together by calcium atoms.
URI: http://www.repositorio.ufop.br/handle/123456789/4166
ISSN: 13861425
Licença: O Periódico Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3487250110168.
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