Please use this identifier to cite or link to this item: http://www.repositorio.ufop.br/jspui/handle/123456789/14303
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dc.contributor.authorCarvalho, Alexandre B. de-
dc.contributor.authorDiogo, Gabriela Maciel-
dc.contributor.authorCorrea, Rodrigo de Souza-
dc.contributor.authorTaylor, Jason Guy-
dc.date.accessioned2022-01-10T17:33:33Z-
dc.date.available2022-01-10T17:33:33Z-
dc.date.issued2020pt_BR
dc.identifier.citationCARVALHO, A. B. de et al. Synthesis and molecular structure of a chiral bipyridine-menthol ether. Journal of Structural Chemistry, v. 61, n. 5, p. 763-768, 2020. Disponível em: <https://link.springer.com/article/10.1134/S0022476620050121>. Acesso em: 10 jun. 2021.pt_BR
dc.identifier.issn1573-8779-
dc.identifier.urihttp://www.repositorio.ufop.br/jspui/handle/123456789/14303-
dc.description.abstractThis paper presents the synthesis and structural characterization of 6,6′-bis[(1R,2S,5R)-isomenthoxy]-2,2′- bipyridine obtained by homocoupling of chiral pyridyl-ether 2-bromo-6-[(1R,2S,5R)-isomenthoxy]- pyridine. The two-step synthetic procedure afforded chiral bipyridine in a good yield and the structure of the compound is determined by X-ray diffraction. It crystallizes in a non-centrosymmetric chiral crystal structure type (P21, a = 10.7543(8) Å, b = 8.4488(6) Å, c = 15.8964(10) Å, β = 104.035(7)°, V = 1401.24(17) Å3 , Z = 2). Moreover, the compound is characterized by FTIR, high resolution mass spectrometry and its complexation capacity to transition metals is studied by UV-Vis spectroscopy.pt_BR
dc.language.isoen_USpt_BR
dc.rightsrestritopt_BR
dc.subjectMentholpt_BR
dc.subjectLigandpt_BR
dc.subjectMetalpt_BR
dc.subjectCrystal structurept_BR
dc.titleSynthesis and molecular structure of a chiral bipyridine-menthol ether.pt_BR
dc.typeArtigo publicado em periodicopt_BR
dc.identifier.uri2https://link.springer.com/article/10.1134/S0022476620050121pt_BR
dc.identifier.doihttps://doi.org/10.1134/S0022476620050121pt_BR
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